X-Ray Fluorescence (XRF) exposes the material to an X-Radiation beam that causes temporary
excitation and emitting of secondary X-Radiation at levels
characteristic for each element in the sample. Measurement and analysis
of the secondary radiation provides the composition of the material
under test. XRF testing leaves no mark or alteration of the tested
material, allowing for measurement non-coated finished goods if
necessary. However, XRF technologies cannot distinguish between
material grades that differ in elements that it cannot measure, such as
Carbon, Silicon, and others.
Optical Emission Spectroscopy (OES) exposes the test sample to excitation through an electrical spark
between the sample and an electrode, most often in an atmosphere of
high purification Argon. The spark energy results in emitted light in
wavelengths and intensity characteristic to the elements in the test
sample. OES analysis offers the most complete view of elements in a
test sample. It is the only method that can distinguish between the
levels of Carbon in a sample. For example, the difference between 316L
and 316H. Although OES is considered a nondestructive test method, the
surface must be prepared by sanding or grinding and the material will
show a small burn mark following a test.